Acta Chimica Slovaca (ACS) publishes papers on fundamental and applied aspects of chemistry, biochemistry, chemical technology, chemical engineering and process control, biotechnology and food technology. Welcome are also topics which include chemical aspects of materials, physical chemistry and chemical physics, analytical chemistry, macromolecular chemistry and biomedical engineering.

Copper(II) 2-Nitrobenzoatecomplexes with Nicotinamide, Preparation and Properties

Jana Medvecká *, Ján Moncoľ, Vladimír Jorík, Kristína Satková, Dušan Valigura

Department of Inorganic Chemistry, FCHPT STU, Radlinského 9, 812 37 Bratislava

E-mail: * jana.medvecka@stuba.sk

Abstract: Two new complexes [Cu(2-NO2bz)2(nia)2] (1), [Cu2(2-NO2bz)4(nia)2]∙(AC) (2) were obtained in addition to known ones [Cu2(2-NO2bz)4(nia)2]∙(ACN) (3) and [Cu(2-NO2bz)2(nia)2(H2O)2] (4) were obtained by the study of copper(II) acetate reactions with nicotinamide (nia) and 2-nitrobenzoic acid in different solvents and using different molar ratios of copper(II) : nia. All complexes under study were characterized by elemental analysis and by IR, or UV/VIS spectra and X-ray powder diffraction pattern were obtained to characterize samples and to compare obtained products with known ones.

Keywords: copper complexes, nicotinamide, 2-nitrobenzoate

Full paper in Portable Document Format: acs_0079.pdf

Acta Chimica Slovaca, Vol. 4, No. 1, 2011, pp. 38—46